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Enhancement of the Hydrogen-Storage Characteristics of Mg by Adding Mg2Ni and Ni to MgH2 via High Energy Ball Milling in Hydrogen Atmosphere
Seong-Hyeon Hong, Young Jun Kwak, Myoung Youp Song
Korean J. Met. Mater. 2018;56(1):59-65.   Published online 2018 Jan 1
DOI: https://doi.org/10.3365/KJMM.2018.56.1.59

Abstract
In this work, Mg2Ni and Ni were added to MgH2 in order to improve the hydrogen-storage properties of Mg. A 94 wt% MgH2+5 wt% Mg2Ni+1wt% Ni (named 94MgH2+5Mg2Ni+1Ni) sample was prepared by milling in a hydrogen atmosphere in a planetary ball mill for 5 h. The Mg2Ni was hydrided during..... More

       Crossref 8
Recovery of Fine Aluminum Hydroxide with High Whiteness Index from Low Quality Bauxite Using Caustic Roasting and Water Leaching
Su Jin Kim, Jeong Il Lee, Kyu Sung Han, So Yeong Byun, Tam Tran, Myong Jun Kim
Korean J. Met. Mater. 2018;56(1):49-58.   Published online 2018 Jan 1
DOI: https://doi.org/10.3365/KJMM.2018.56.1.49

Abstract
A bauxite of low quality containing 6.75% reactive silica and 37.4% Al2O3 as gibbsite was roasted with additives including NaOH (caustic/total alumina molar ratio of 2-4:1) and CaO (CaO/total SiO2 molar ratio of 0.5-3:1) at 300-1000 oC, producing calcines containing sodium aluminate (Na2O.Al2O3), silicates and hematite. Optimum conditions included roasting..... More

       Crossref 2
Study on the Water Durability of Molybdate Glasses with B2O3 as Low Temperature Sealing Materials
Jae-Young Shin, Jae-Min Cha, Dae-Sung Kim, Dea-Geol Jeong, Jun-Hyeon Bae, Bong-Ki Ryu
Korean J. Met. Mater. 2017;55(12):905-910.   Published online 2017 Dec 4
DOI: https://doi.org/10.3365/KJMM.2017.55.12.905

Abstract
The boron alkali molybdate glass system was investigated as lead-free low-temperature melting sealing materials, with different boron oxide contents between 0 and 8 mol%. The glasses were characterized using X-ray diffraction (XRD), differential scanning calorimetry (DSC), infrared spectroscopy (IR), and by densities. Their chemical properties were measured by their dissolution..... More

    
AISI 304 Steel Brazing Using A Flexible Brazing Foil Fabricated by Tape Casting Method
Ashutosh Sharma, Soon-Jae Lee, Joo-Hee Oh, Jae Pil Jung
Korean J. Met. Mater. 2017;55(12):836-844.   Published online 2017 Dec 4
DOI: https://doi.org/10.3365/KJMM.2017.55.12.836

Abstract
The authors report the fabrication of a flexible nickel brazing foil using powdered nickel alloy filler (BNi-2) mixed with an organic binder. The organic binder was composed of a polyacrylic acid polymer, glycol, carbon tetrachloride, and water as a dispersion medium for the powder. The brazing paste so formed was..... More

       Crossref 1
Role of Voltage and Gas Pressure in Determining the Mean Diameter of Sn-Bi-Ag Intermetallic Compound Nanoparticles Formed by Pulsed Wire Discharge
Dae Geol Jeong, Jae Min Cha, Dae Sung Kim, Ju Hyeong Kim, Hwa Jin Jeong, Jae Young Shin, Jun Hyeon Bae, Bong Ki Ryu, Hisayuki Suematsu, Kenta Tanaka
Korean J. Met. Mater. 2017;55(11):806-812.   Published online 2017 Oct 31
DOI: https://doi.org/10.3365/KJMM.2017.55.11.806

Abstract
Nanoscale Sn-Bi-Ag compound powders were successfully synthesized using the pulsed wire discharge (PWD) method. In PWD, when a high current is passed through high-density metal wires, the wires explode because of resistance heating, forming fine particles or metal vapor. In this study, we used Sn-Bi and Ag wires in order..... More

    
Pulsed Electrodeposition of Thin Cobalt Coating Layer on Ferritic Stainless Steel for SOFC Interconnects
Suk-Chul Kwak, Byung Kyu Kim, Dong-Ik Kim, Young Whan Cho
Korean J. Met. Mater. 2017;55(11):768-776.   Published online 2017 Oct 31
DOI: https://doi.org/10.3365/KJMM.2017.55.11.768

Abstract
A thin, compact, and uniform cobalt layer was coated on ferritic stainless steel (Crofer 22 APU) by high frequency square pulsed electrodeposition in an aqueous solution containing cobalt chloride and boric acid. The effects of various electrodeposition parameters and post heat treatment on the morphology, thickness, roughness and adhesion of..... More

    
Material Characterization of Single Crystalline Cu Subjected to High Strain Rates and High Temperatures for Multiscale Simulation
Yujin Seong, Youngkyu Kim, Im Doo Jung, Sungho Kim, See Jo Kim, Seong-Gon Kim, Hak Jun Kim, Seong Jin Park
Korean J. Met. Mater. 2017;55(11):760-767.   Published online 2017 Oct 31
DOI: https://doi.org/10.3365/KJMM.2017.55.11.760

Abstract
The material characterization of single crystalline Cu columns was numerically carried out at the submicroscopic level. A molecular dynamics (MD) simulation was employed using the embedded-atom method (EAM) interatomic potential between a pair of Cu atoms to describe the interactions among Cu atoms. First, the relationship between mechanical properties and..... More

       Crossref 1
Separation of Rhenium (VII) and Vanadium (V) from Hydrochloric Acid Solutions by Solvent Extraction
Thi Hong Nguyen, Hoai Thanh Truong, Man Seung Lee
Korean J. Met. Mater. 2017;55(10):724-731.   Published online 2017 Sep 28
DOI: https://doi.org/10.3365/KJMM.2017.55.10.724

Abstract
The separation of Re(VII) and V(V) by solvent extraction with TBP was investigated by varying the HCl, metal and chloride ion concentrations. Re(VII) was selectively extracted over V(V) from the HCl solution. The highest separation between Re(VII) and V(V) occurred at a concentration of 2.0 M HCl. The extraction reaction..... More

       Crossref 1
Inhomogeneous Deformation of Interstitial Free Steel during the High Pressure Torsion Process
Yuepeng Song, Miaomiao Chen, Wenke Wang, Baoyan Xu, Dongsheng Gao, Shuai Zhang, Hyoung Seop Kim
Korean J. Met. Mater. 2017;55(10):710-715.   Published online 2017 Sep 28
DOI: https://doi.org/10.3365/KJMM.2017.55.10.710

Abstract
Interstitial free (IF) steel disks were subjected to various degrees of revolution during application of the high-pressure torsion (HPT) process, and the resulting distributions of hardness and microstructure during the early torsion stage of high-pressure torsion (HPT) were investigated using experimental and simulation approaches. The results indicated that the deformation..... More

    
Increase in the Hydrogen-Sorption Rates and the Hydrogen-Storage Capacity of MgH2 by Adding a Small Proportion of Zn(BH4)2
Hye Ryoung Park, Young Jun Kwak, Myoung Youp Song
Korean J. Met. Mater. 2017;55(9):657-663.   Published online 2017 Aug 30
DOI: https://doi.org/10.3365/KJMM.2017.55.9.657

Abstract
Abstract: In this work, Zn(BH4)2 was added to improve the hydrogen-storage properties of MgH2. A 99 wt% MgH2+1 wt% Zn(BH4)2 sample was prepared by milling in a planetary ball mill in a hydrogen atmosphere. The proportion of the added Zn(BH4)2 was small (1 wt%) in order to increase hydriding and..... More

       Crossref 2
Review of Conductive Copper Paste for c-Si Solar Cells
Sang Hee Lee, Doo Won Lee, Soo Hong Lee
Korean J. Met. Mater. 2017;55(9):637-644.   Published online 2017 Aug 30
DOI: https://doi.org/10.3365/KJMM.2017.55.9.637

Abstract
In the photovoltaic industries, the main technique of metallization is screen printing with silver pastes, due to its simple and quick process. However, the high price of silver paste is one of the barriers to the producing of low cost solar cells. Consequently, a primary target in photovoltaic research is..... More

       Crossref 3
Wetting Behavior of Liquids on Micro-Patterned Polymer Surfaces Fabricated by Thermal Imprinting
Kwang-Jin Bae, Wenhui Yao, Yiliang He, Young-Rae Cho
Korean J. Met. Mater. 2017;55(9):624-631.   Published online 2017 Aug 30
DOI: https://doi.org/10.3365/KJMM.2017.55.9.624

Abstract
The wetting behavior of liquids on solid surfaces is important in the study of surfaces and interfaces. In this study, the wetting behavior of deionized (DI) water and hexadecane on fluorinated and micro-patterned polymer surfaces was investigated. The sample surfaces were processed by spray coating and thermal imprinting, respectively. The..... More

       Crossref 1
Hydrogen-Affected Tensile and Fatigue Properties of Ti-6Al-4V Sheets by Superplastic Forming
Jinil Son, Junhyuk Park, Daeho Jeong, Yongnam Kwon, Masahiro Goto, Sangshik Kim
Korean J. Met. Mater. 2017;55(9):615-623.   Published online 2017 Aug 30
DOI: https://doi.org/10.3365/KJMM.2017.55.9.615

Abstract
Mill-annealed Ti-6Al-4V (Ti64) sheets were formed into rectangular shaped pans with two square recesses by the superplastic forming (SPF) technique under high pressure using commercial grade argon gas. The SPF process induced a significant decrease in the tensile ductility and high cycle fatigue (HCF) resistance of the Ti64 alloy. The..... More

    
Near Infrared Reflecting Properties of TiO2/Ag/TiO2 Multilayers Prepared by DC/RF Magnetron Sputtering
Sung Han Kim, Seo Han Kim, Pung Keun Song
Korean J. Met. Mater. 2017;55(8):581-586.   Published online 2017 Aug 1
DOI: https://doi.org/10.3365/KJMM.2017.55.8.581

Abstract
The near-infrared (NIR) reflecting properties of TiO2 /Ag /TiO2 (TAT) multilayers deposited using DC/RF magnetron sputtering were investigated. For high transmittance and reflectance in the visible and NIR ranges, respectively, the thickness of each layer was theoretically optimized by the index matching method. As the Ag layer thickness increased, the..... More

    
Direct Laser Deposition of 14Cr Oxide Dispersion Strengthened Steel Powders Using Y2O3 and HfO2 Dispersoids
Barton Mensah Arkhurst, Jin-Ju Park, Chang-Hoon Lee, Jeoung Han Kim
Korean J. Met. Mater. 2017;55(8):550-558.   Published online 2017 Aug 1
DOI: https://doi.org/10.3365/KJMM.2017.55.8.550

Abstract
This study investigated the feasibility of using HfO2 as a dispersoid in the additive manufacturing process, compared to Y2O3. The effect of pre-annealing treatment was investigated too. Scanning electron microscopy (SEM) analyses revealed unusually coarse deposition layers for both the HfO2 and Y2O3 dispersed oxide dispersion strengthed (ODS) steels, in..... More

       Crossref 4
Enhanced Resistance to Delayed Cracking in Deep-drawn Lean Duplex Stainless Steel: the Role of Residual Stress
Seok Hwan Jung, Taekyung Lee, Seok Weon Song, Young Jin Kwon, Hyung-Gu Kang, Dongchul Chae, Chong Soo Lee
Korean J. Met. Mater. 2017;55(8):544-549.   Published online 2017 Aug 1
DOI: https://doi.org/10.3365/KJMM.2017.55.8.544

Abstract
The delayed cracking behavior of deep-drawn lean duplex stainless steel (LDSS) was investigated, and compared with that of conventional metastable austenitic stainless steels (MASS). Hydrogen charging was performed by electrochemical method, and the hydrogen-charged specimens were subjected to the slow-strain-rate test. Fractures occurred along the phase boundaries in the LDSS,..... More

       Crossref 2
Effect of E-Beams Irradiation Dose on the Sensing Properties of Pt-Functionalized Reduced Graphene Oxides Following Annealing of the 6 nm-Thick Pt Layer
Yong Jung Kwon, Ali Mirzaei, Han Gil Na, Sung Yong Kang, Myung Sik Choi, Jae Hoon Bang, Jaegab Lee, Inpil Kang, Sang Sub Kim, Hyoun Woo Kim
Korean J. Met. Mater. 2017;55(7):492-502.   Published online 2017 Jul 4
DOI: https://doi.org/10.3365/KJMM.2017.55.7.492

Abstract
Pt-functionalized RGO samples were prepared and subsequently irradiated with 2-MeV electron beams (e-beams). The effect of e-beam dose on the structural, electrical, and gas sensing properties of the samples was investigated. E-beam irradiation was found to induce significant microstructural changes in the Pt-functionalized RGO. Measurements of NO2 sensing at room..... More

       Crossref 2
Microstructural Changes of 22Cr-9Mo-3Fe-4Nb Ni-Base Superalloy during Creep
Youngseok Song, Jinik Suk, Chung-Yun Kang
Korean J. Met. Mater. 2017;55(7):486-491.   Published online 2017 Jul 4
DOI: https://doi.org/10.3365/KJMM.2017.55.7.486

Abstract
A new Ni based superalloy is considered as bucket material because of high fatigue resistance with fine grain. However a bucket is usually exposed to high temperature for a long time, so creep rupture tests were conducted to understand the microstructure evolution during creep deformation under various stresses at temperatures..... More

       Crossref 1
Solvent Extraction of Tungsten(VI) from Moderate Hydrochloric Acid Solutions with LIX 63
Hoai Thanh Truong, Yong Hwan Kim, Man Seung Lee
Korean J. Met. Mater. 2017;55(6):405-411.   Published online 2017 Jun 1
DOI: https://doi.org/10.3365/KJMM.2017.55.6.405

Abstract
The solvent extraction of tungsten(VI) from hydrochloric acid solutions using 5,8-diethyl- 7-hydroxydodecan-6-one oxime (LIX 63) was analyzed in solutions having an initial pH range from 2 to 5, by varying the concentration of metal and extractant. In our experimental range, the cationic exchange reaction as well as the solvation reaction..... More

       Crossref 5
Fabrication of Porous Titania Particles from Complex Fluids by Spray Drying Process and Their Applications
Young-Sang Cho
Korean J. Met. Mater. 2017;55(4):264-273.   Published online 2017 Apr 6
DOI: https://doi.org/10.3365/KJMM.2017.55.4.264

Abstract
In this study, a spray drying system was used to prepare macroporous titania micro-particles for applications including UV blocking materials and photocatalysts. To synthesize the macroporous particles a colloidal templating method using polymeric beads as sacrificial templates and a titania nano-colloid as precursor material was adopted. The resulting porous titania..... More

       Crossref 1
Separation and Recovery of Precious Metals from Leach Liquors of Spent Electronic Wastes by Solvent Extraction
Thi Hong Nguyen, Lingyun Wang, Man Seung Lee
Korean J. Met. Mater. 2017;55(4):247-255.   Published online 2017 Apr 6
DOI: https://doi.org/10.3365/KJMM.2017.55.4.247

Abstract
Solvent extraction was employed to recover precious metals (Au (III), Pd (II) and Pt (IV)) from the leach solution of spent electronic wastes containing Cu (II), Cr (III) and Fe (III). First, pure Fe (III) and Au (III) were recovered by simultaneous extraction with Cyanex 923 followed by selective stripping..... More

       Crossref 16
High-temperature Corrosion of AlCrTiSiN Film in Ar-1%SO2 Gas
Poonam Yadav, Sik Chol Kwon, Yue Lin, Shihong Zhang, Dong Bok Lee
Korean J. Met. Mater. 2017;55(4):222-226.   Published online 2017 Apr 6
DOI: https://doi.org/10.3365/KJMM.2017.55.4.222

Abstract
An AlCrTiSiN film composed of 31Al-15Cr-1.7Ti-0.5Si-51.8N (at%) was deposited on a steel substrate by arc ion plating to a thickness of 1 μm. It consisted of nano crystalline hcp-AlN and fcc-CrN. Its corrosion behavior in Ar-1%SO2 gas at 800 ℃ for 5-50 h was studied. The resulting scales consisted primarily..... More

    
Enhancement of the Opto-Electrical Properties of Ag Intermediate ZTO Films by Vacuum Annealing
Hyun-Joo Moon, Daeil Kim
Korean J. Met. Mater. 2017;55(3):209-212.   Published online 2017 Mar 3
DOI: https://doi.org/10.3365/KJMM.2017.55.3.209

Abstract
Sn-doped ZnO (ZTO)/Ag/ZTO tri-layer films were deposited on glass substrates by radio frequency (RF) and direct current (DC) magnetron sputtering and then vacuum annealed at 100, 200 and 300 ℃ for 30 min with a proportions of H2/N2 gas flow of 6/6 sccm, to investigate the effects of annealing temperature..... More

    
Simulation and Experimental Study on the Steady Conduction Solution for Continuous Rheo-Casting for A356 Alloy
Do Minh Duc, Nguyen Hong Hai, Pham Quang
Korean J. Met. Mater. 2017;55(3):202-208.   Published online 2017 Mar 3
DOI: https://doi.org/10.3365/KJMM.2017.55.3.202

Abstract
Computational fluid dynamic modeling of a continuous rheo-casting technology was conducted, consistent with the manufacturing of 3 mm-thin plates made of aluminum alloy A356. The A numerical simulation on of the stabilizing time of the material crystallization was carried out using the ANSYS FLUENT code. Solidification and melting models were..... More

    
The Effect of Al and V on Microstructure and Transformation of β Phase during Solution Treatments of Cast Ti-6Al-4V Alloy
Seong-Tak Oh, Kee-Do Woo, Jae-Hwang Kim, Seung-Mi Kwak
Korean J. Met. Mater. 2017;55(3):150-155.   Published online 2017 Mar 3
DOI: https://doi.org/10.3365/KJMM.2017.55.3.150

Abstract
In this study, the effect of α and β those stabilizers on the microstructure and phase transformation of cast Ti-6wt%Al-4wt%V alloy at various solution treatment temperatures was investigated. The dependence of the transformation behavior of the β phase during the solution treatment and its dependence was determined by the partitioning..... More

       Crossref 3
Effect of Added Gas-Atomized Al-Si/SiCp Composite Powder on the Sinterability and Mechanical Properties of Alumix 431 fabricated by Hot-Pressing Process
Eunsun Lee, Jeong-Jung Oak, Yongjin Kim, Yongho Park
Korean J. Met. Mater. 2017;55(2):98-109.   Published online 2017 Feb 2
DOI: https://doi.org/10.3365/KJMM.2017.55.2.98

Abstract
The aim of this study is to establish an optimized hot-press sintering condition for aluminum matrix composites (AMCs) by analyzing their sintered microstructure and mechanical properties. The fabricated AMCs in this study consisted of a blend of commercial Ecka Alumix 431 powder, and Al-Si/SiCp powder manufactured by gas atomizer (Al-Si/SiCp)...... More

       Crossref 1
Material Analysis & Characterization
Structural Analysis of Three-Component Nanoparticles of Sn-58Bi and Cu Wires Prepared by Pulsed Wire Discharge
Jong Hwan Kim, Dae Sung Kim, Hisayuki Suematsu, Kenta Tanaka, Bong Ki Ryu
Korean J. Met. Mater. 2017;55(1):72-76.   Published online 2017 Jan 5
DOI: https://doi.org/10.3365/KJMM.2017.55.1.72

Abstract
We used Sn-58Bi and Cu wires to investigate the effects of variable conditions (such as pressure and wire diameter) on the formation of three-component nanoparticles. In the synthesis of the three-component nanoparticles, pulsed wire discharge was used to sublimate the wires. In this system, the K factor is described as..... More

       Crossref 1
Effects of Doping Concentration on the Structural and Optical Properties of Spin-Coated In-doped ZnO Thin Films Grown on Thermally Oxidized ZnO Film/ZnO Buffer Layer/Mica Substrate
Byunggu Kim, Jae-Young Leem
Korean J. Met. Mater. 2017;55(1):67-71.   Published online 2017 Jan 5
DOI: https://doi.org/10.3365/KJMM.2017.55.1.67

Abstract
ZnO buffer layers were deposited on mica substrates using a sol-gel spin coating method. Then, a thin film of metallic Zn was deposited onto the ZnO buffer layer/mica substrate using a thermal evaporator, and the deposited Zn thin films were then thermally oxidized in a furnace at 500 ℃ for..... More

       Crossref 1
Hydrogen Sorption of Pure Mg and Niobium (V) Fluoride-Added Mg Alloys Prepared by Planetary Ball Milling in Hydrogen
Hye Ryoung Park, Young Jun Kwak, Seong Ho Lee, Myoung Youp Song
Korean J. Met. Mater. 2016;54(12):916-924.   Published online 2016 Dec 5
DOI: https://doi.org/10.3365/KJMM.2016.54.12.916

Abstract
In this work, niobium (V) fluoride was selected as an additive to heighten the hydrogen sorption rates of Mg. Specimens of pure Mg, 5 wt% niobium fluoride-added Mg, and 10 wt% niobium fluoride-added Mg were prepared by planetary ball milling in hydrogen. The hydrogen sorption properties of the specimens were..... More

       Crossref 5
Effects of Friction and Anvil Design on Plastic Deformation during the Compression Stage of High-Pressure Torsion
Yuepeng Song, Miaomiao Chen, Baoyan Xu, Dongsheng Gao, Jing Guo, Lingfeng Xu, Zheng Wang, Hyoung Seop Kim
Korean J. Met. Mater. 2016;54(11):831-837.   Published online 2016 Nov 5
DOI: https://doi.org/10.3365/KJMM.2016.54.11.831

Abstract
Herein, we report the results of our investigation on the effect of friction and anvil design on the heterogeneous plastic-deformation characteristics of copper during the compressive stage of high-pressure torsion (HPT), using the finite element method. The results indicate that the friction and anvil geometry play important roles in the..... More

       Crossref 3
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